Unexpected Coexisting Solid Solutions in the Quasi‐binary Ag<sup>(II)</sup>F<sub>2</sub>/Cu<sup>(II)</sup>F<sub>2</sub> Phase Diagram
نویسندگان
چکیده
In the presence of F2 overpressure, at elevated temperature, and despite similarity their crystal structures, CuF2 AgF2 unexpectedly form two distinct solid solutions, (Cu1−xAgx)F2 (Ag1−xCux)F2. Each phase shows different mutual solubility Cu2+ Ag2+ (shown as yellow violet balls), magnetic properties are strongly impacted by this seemingly simple isoelectronic substitution. More information can be found in Research Article Z. Mazej, J. Lorenzana, W. Grochala, co-workers (DOI: 10.1002/chem.202301092). Cover image: Małgorzata Fürst.
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ژورنال
عنوان ژورنال: Chemistry: A European Journal
سال: 2023
ISSN: ['0947-6539', '1521-3765']
DOI: https://doi.org/10.1002/chem.202302509